Friday, 18 July 2025 11:00am – 12:00pm

This seminar will be delivered in New Law Annex Lecture Theatre 104

Speaker: Dr Shurui Miao

Host: Dr Alexander Djerdjev

Title: Electrolyte under nanoscopic confinement and why it matters for tackling climate change

Abstract
Accelerated carbon mineralisation recently emerged as a promising approach for long-term carbon sequestration. This process involves reacting naturally abundant minerals (e.g. basalt, rich in Ca²⁺ and Mg²⁺) with aqueous CO₂ solution to form stable carbonate minerals.[1] However, its molecular mechanism remains largely unknown due to the lack of direct experimental data probing structures and forces near the solid-liquid interface.[2] Nonclassical 2-steps crystallisation is now widely recognised as pathways of carbonate mineral formation.[3-5] A common feature to such nonclassical mechanism is the formation of ionic clusters prior to crystallisation. The formation of these hydrated clusters and the drainage of solvents are closely related to the ordering of the water near the solid-solution interface. Our work uses surface force balance to measure the force between mineral surfaces across electrolyte solutions with micro-Newton and Angstrom precision. We observed unexpected long-range repulsive forces that cannot be explained by the Derjaguin-Landau-Verwey-Overbeek theory, and it is insensitive to ionic strength (beyond a threshold concentration) and pH. Our work provides key experimental results and insights to understand the specific ion effects at the solid-liquid interface, which is critical to the design and engineering of solution processes and colloidal systems such as carbon mineralisation.

References

1. M. Matter, et al., Science 352, 1312-1314 (2016)
2. J. De Yoreo, et al., Science 349, aaa6760 (2015)
3. J. M. Smeets, et al., PNAS, 114 (38) E7882-E7890 (2017)
4. Jiang, et al., J. Chem. Phys. 150, 124502 (2019)
5. Jin., et al. Nat. Mater. 24, 125-132 (2025)

Bio
Shurui is currently a Junior Research Fellow in Chemistry at St John’s College, University of Oxford. He completed his PhD at the University of Sydney worked with Prof. Gregory Warr. In December 2022, Shurui joined the Group of Prof. Susan Perkin at Oxford as a postdoc before being awarded his Fellowship in 2024. He’s research interest is centred around better understanding concentrated electrolytes for sustainable development and have been recognised through awards including the ISIS Neutron and Muon Source Springboard Award.